Surroundings: That portion of the universe which does not include the system in question. Thus, a universe consists of a system and its surroundings.
Spontaneous process: A process which requires no influence from outside the system to proceed. A process which can proceed in an isolated system.
Nonspontaneous process: A process which does require influence from outside the system to proceed. This process is impossible in an isolated system.
Equilibrium: A condition in which there is
no net change in any of the state functions of a system which has been allowed
to arrive at rest with its surroundings.